%0 Journal Article %A S. Dorokhov, Valentin %A Jung, Hoimin %A A. Andreev, Yury %A Semakin, Artem N. %A Oh, Jinho %A Sukhorukov, Alexey Yu. %A Ioffe, Sema L. %A E. Semenov, Sergey %A Kang, Gyumin %D 2015 %T Synthesis of Tris(ɣ-oximinoalkyl)amines, New Tripodal N4 Ligands %U https://tandf.figshare.com/articles/journal_contribution/Synthesis_of_Tris_611_oximinoalkyl_amines_New_Tripodal_N4_Ligands/1314931 %R 10.6084/m9.figshare.1314931.v2 %2 https://tandf.figshare.com/ndownloader/files/2023577 %K methyl vinyl ketone %K ligand %K sequence %K hydroxylamine %K new %K ammonia %K tris %K approach %K synthesis %K N 4 tripodal ligands %K tripodal %K Synthesi %K oximation %X

An original approach to the synthesis of tris(γ-oximinoalkyl)amines was proposed. The suggested synthetic sequence is based on aza-Michael addition of ammonia to methyl vinyl ketone and oximation of obtained products with hydroxylamine or O-alkhylhydroxylamines. The tris(γ-oximinoalkyl)amines may be considered as prospective N4 tripodal ligands.

%I Taylor & Francis