10.6084/m9.figshare.1568933.v5 Nina A. Lenshina Nina A. Lenshina Margarita P. Shurygina Margarita P. Shurygina Maxim V. Arsenyev Maxim V. Arsenyev Andrey I. Poddel’sky Andrey I. Poddel’sky Sergey D. Zaitsev Sergey D. Zaitsev Sergey A. Chesnokov Sergey A. Chesnokov Gleb A. Abakumov Gleb A. Abakumov Optically controlled distribution of <i>o</i>-quinonemethacrylate metal complexes in polymer materials Taylor & Francis Group 2015 polymer ethylene glycol monomethacrylate 4VO film nh thf copolymer solution molybdenum complexes 2015-11-24 14:31:49 Journal contribution https://tandf.figshare.com/articles/journal_contribution/Optically_controlled_distribution_of_i_o_i_quinonemethacrylate_metal_complexes_in_polymer_materials/1568933 <div><p>The complexation ability of photoreduction products of 2-(2,5-di-<i>tert</i>-butyl-3,4-dioxycyclohexa-1,5-dienyl)ethyl methacrylate in tetrahydrofuran (THF) solution and in its copolymer films with dimethacrylate and ethylene glycol monomethacrylate was studied. The product of photochemical reduction – catechol – reacts with (NH<sub>4</sub>)<sub>6</sub>Mo<sub>7</sub>O<sub>24</sub>·4H<sub>2</sub>O, NH<sub>4</sub>VO<sub>3</sub> and (NH<sub>4</sub>)<sub>2</sub>Fe(SO<sub>4</sub>)<sub>2</sub> with the formation of corresponding metal complexes in solution and in the polymer bulk. The concentration of the molybdenum complexes in the polymer matrix was proportional to the exposure and holding time in solution of molybdate salt. Polymer film with optically controlled distribution of <i>o</i>-quinonemethacrylate molybdenum complexes was prepared. A film containing antimony and molybdenum complexes together in the polymer structure in predetermined ratio was obtained by sequential treatment of irradiated copolymer film (50% conversion) by THF solution of SbPh<sub>3</sub>, and water solution of (NH<sub>4</sub>)<sub>6</sub>Mo<sub>7</sub>O<sub>24</sub>·4H<sub>2</sub>O.</p></div>