10.6084/m9.figshare.5040313.v1
Katarzyna Koroniak-Szejn
Katarzyna
Koroniak-Szejn
Joanna Tomaszewska
Joanna
Tomaszewska
Henryk Koroniak
Henryk
Koroniak
The synthesis of new fluorinated or nonfluorinated sugar phosphonates and phosphoramidates as building blocks in the synthesis of modified hyaluronic acid subunits
Taylor & Francis Group
2017
Arbuzov reaction
fluorinated sugar phosphonates
fluorinated sugar phosphoramidates
neighboring group participation
2017-05-25 17:34:46
Journal contribution
https://tandf.figshare.com/articles/journal_contribution/The_synthesis_of_new_fluorinated_or_nonfluorinated_sugar_phosphonates_and_phosphoramidates_as_building_blocks_in_the_synthesis_of_modified_hyaluronic_acid_subunits/5040313
<p></p> <p>The synthesis of several new fluorinated or nonfluorinated sugar phosphonates and phosphoramidates as building blocks for the synthesis of modified hyaluronic acid subunits is described. These compounds were prepared from d-glucose and d-glucosamine hydrochloride. The syntheses of phosphonates and phosphoramidates are based on arbuzov and staudinger reactions. The products were fully characterized by <sup>1</sup>H, <sup>13</sup>C, <sup>19</sup>F, <sup>31</sup>P NMR, and ESI MS spectroscopy.</p>