Oxidative cyanide-free cyanation on arylboronic acid derivatives using aryl/heteroaryl thiocyanate using novel IL-PdCl<sub>4</sub> catalyst under mild condition
Beena K. Vaghasiya
Shailesh P. Satasia
Rahul P. Thummar
Ronak D. Kamani
Jemin R. Avalani
Nirav H. Sapariya
Dipak K. Raval
10.6084/m9.figshare.6244367.v1
https://tandf.figshare.com/articles/journal_contribution/Oxidative_cyanide-free_cyanation_on_arylboronic_acid_derivatives_using_aryl_heteroaryl_thiocyanate_using_novel_IL-PdCl_sub_4_sub_catalyst_under_mild_condition/6244367
<p>An efficient and simple method is reported for the cyanation on arylboronic acid using various simple/indole thiocyanates using a new IL-PdCl<sub>4</sub> catalyst. The cascade process involves a coupling reaction without any additive to give a wide range of cyanide derivatives. Cyanation on various arylboronic acids underwent smoothly affording the corresponding arylnitriles in good to high yields.</p>
2018-05-10 06:40:11
Thiocyanation
IL-PdCl4
FE-SEM
arylboronic acid
indoline derivatives