10.6084/m9.figshare.6637148.v1 Hui Li Hui Li Chen-Zhong Yao Chen-Zhong Yao Xiao-Chuan Chai Xiao-Chuan Chai Gao-Feng Wang Gao-Feng Wang Jun Li Jun Li Jie Wang Jie Wang Zhuang-Wei Wei Zhuang-Wei Wei Fu-Lin Zhou Fu-Lin Zhou Synthesis and characterization of diiron propanedithiolate complexes with monosubstituted tris(2-furyl)phosphine or n-propyldiphenylphosphine Taylor & Francis Group 2018 Carbonyl substitution crystal structure diiron propanedithiolate monophosphine ligand synthesis 2018-06-21 17:46:49 Journal contribution https://tandf.figshare.com/articles/journal_contribution/Synthesis_and_characterization_of_diiron_propanedithiolate_complexes_with_monosubstituted_tris_2-furyl_phosphine_or_n-propyldiphenylphosphine/6637148 <p>Two monosubstituted diiron complexes, namely (<i>µ</i>-SCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>S-<i>µ</i>)Fe<sub>2</sub>(CO)<sub>5</sub>L (L = P(2-C<sub>4</sub>H<sub>3</sub>O)<sub>3</sub>, <b>2</b>; Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub>, <b>3</b>), have been prepared by the carbonyl substitution of the parent complex (<i>µ</i>-SCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>S-<i>µ</i>)Fe<sub>2</sub>(CO)<sub>6</sub> (<b>1</b>) with the corresponding monophosphine ligands in the presence of Me<sub>3</sub>NO·2H<sub>2</sub>O. The new complexes were characterized by elemental analysis, spectroscopy and single crystal X-ray diffraction analysis.</p>