10.6084/m9.figshare.6637148.v1
Hui Li
Hui
Li
Chen-Zhong Yao
Chen-Zhong
Yao
Xiao-Chuan Chai
Xiao-Chuan
Chai
Gao-Feng Wang
Gao-Feng
Wang
Jun Li
Jun
Li
Jie Wang
Jie
Wang
Zhuang-Wei Wei
Zhuang-Wei
Wei
Fu-Lin Zhou
Fu-Lin
Zhou
Synthesis and characterization of diiron propanedithiolate complexes with monosubstituted tris(2-furyl)phosphine or n-propyldiphenylphosphine
Taylor & Francis Group
2018
Carbonyl substitution
crystal structure
diiron propanedithiolate
monophosphine ligand
synthesis
2018-06-21 17:46:49
Journal contribution
https://tandf.figshare.com/articles/journal_contribution/Synthesis_and_characterization_of_diiron_propanedithiolate_complexes_with_monosubstituted_tris_2-furyl_phosphine_or_n-propyldiphenylphosphine/6637148
<p>Two monosubstituted diiron complexes, namely (<i>µ</i>-SCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>S-<i>µ</i>)Fe<sub>2</sub>(CO)<sub>5</sub>L (L = P(2-C<sub>4</sub>H<sub>3</sub>O)<sub>3</sub>, <b>2</b>; Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub>, <b>3</b>), have been prepared by the carbonyl substitution of the parent complex (<i>µ</i>-SCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>S-<i>µ</i>)Fe<sub>2</sub>(CO)<sub>6</sub> (<b>1</b>) with the corresponding monophosphine ligands in the presence of Me<sub>3</sub>NO·2H<sub>2</sub>O. The new complexes were characterized by elemental analysis, spectroscopy and single crystal X-ray diffraction analysis.</p>