Synthesis and characterization of diiron propanedithiolate complexes with monosubstituted tris(2-furyl)phosphine or n-propyldiphenylphosphine
Hui Li
Chen-Zhong Yao
Xiao-Chuan Chai
Gao-Feng Wang
Jun Li
Jie Wang
Zhuang-Wei Wei
Fu-Lin Zhou
10.6084/m9.figshare.6637148.v1
https://tandf.figshare.com/articles/journal_contribution/Synthesis_and_characterization_of_diiron_propanedithiolate_complexes_with_monosubstituted_tris_2-furyl_phosphine_or_n-propyldiphenylphosphine/6637148
<p>Two monosubstituted diiron complexes, namely (<i>µ</i>-SCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>S-<i>µ</i>)Fe<sub>2</sub>(CO)<sub>5</sub>L (L = P(2-C<sub>4</sub>H<sub>3</sub>O)<sub>3</sub>, <b>2</b>; Ph<sub>2</sub>PCH<sub>2</sub>CH<sub>2</sub>CH<sub>3</sub>, <b>3</b>), have been prepared by the carbonyl substitution of the parent complex (<i>µ</i>-SCH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>S-<i>µ</i>)Fe<sub>2</sub>(CO)<sub>6</sub> (<b>1</b>) with the corresponding monophosphine ligands in the presence of Me<sub>3</sub>NO·2H<sub>2</sub>O. The new complexes were characterized by elemental analysis, spectroscopy and single crystal X-ray diffraction analysis.</p>
2018-06-21 17:46:49
Carbonyl substitution
crystal structure
diiron propanedithiolate
monophosphine ligand
synthesis