The synthesis of 1-biphenyl-4-alkyl-[1,2,3]-triazoles and their mesomorphic behaviour Kunlun Wang Mirosław Salamończyk Antal Jákli Samuel Sprunt Robert J. Twieg 10.6084/m9.figshare.7849769.v1 https://tandf.figshare.com/articles/journal_contribution/The_synthesis_of_1-biphenyl-4-alkyl-_1_2_3_-triazoles_and_their_mesomorphic_behaviour/7849769 <p>A series of 1-biphenyl-4-alkyl-[1,2,3]-triazole-based liquid crystal compounds were synthesised via a fast and efficient microwave mediated ‘Click Reaction’ and their phase behaviour is presented. Most of the 1-(3-fluorobiphenyl)-4-alkyl-[1,2,3]-triazole compounds exhibited a smectic A phase with relatively low transition temperatures compared to previously examined aryl-triazole-based mesogens. Small angle X-ray scattering measurement indicated the existence of deep smectic phase for some cases. Structural variations gave rise to different phase behaviour in these triazole-based compounds.</p> 2019-03-15 05:06:01 Triazole small angle X-ray scattering smectic A structural variations