%0 Journal Article %A M. Markitanov, Yuriy %A Timoshenko, Vadim M. %A Rudenko, Tymofii V. %A Rusanov, Eduard B. %A Shermolovich, Yuriy G. %D 2019 %T 3-Functional substituted 4-trifluoromethyl tetrahydrothiophenes via [3 + 2]-cycloaddition reactions %U https://tandf.figshare.com/articles/journal_contribution/3-Functional_substituted_4-trifluoromethyl_tetrahydrothiophenes_via_3_2_-cycloaddition_reactions/8331509 %R 10.6084/m9.figshare.8331509.v1 %2 https://tandf.figshare.com/ndownloader/files/15613631 %K Tetrahydrothiophene %K thiocarbonyl ylide %K cycloaddition %K sulfonamide %K sulfoximine %K sulfone %K phosphonate %K trifluoromethyl group %X

New 4-(trifluoromethyl)tetrahydrothiophenes containing an ester, sulfone, sulfoximine, sulfonamide, or phosphonate moiety at position 3 were synthesized by 1,3-dipolar [3 + 2]-cycloaddition reactions of 3,3,3-trifluoropropene derivatives and thiocarbonyl ylide generated in situ from chloromethyl trimethylsilylmethyl sulfide.

%I Taylor & Francis