10.6084/m9.figshare.9508895.v1
Yong Wang
Yong
Wang
Huaxin Zhao
Huaxin
Zhao
Xiaojuan Xie
Xiaojuan
Xie
Haizhen Jiang
Haizhen
Jiang
Hongmei Deng
Hongmei
Deng
Jian Hao
Jian
Hao
Wen Wan
Wen
Wan
Silver-catalyzed decarboxylative homocoupling reaction for the construction of tetrafluoroethylene-bridging aromatic compounds
Taylor & Francis Group
2019
Decarboxylative homocoupling
difluoroacetate
radical dimerization
tetrafluoroethylene bridge
2019-08-12 07:39:58
Journal contribution
https://tandf.figshare.com/articles/journal_contribution/Silver-catalyzed_decarboxylative_homocoupling_reaction_for_the_construction_of_tetrafluoroethylene-bridging_aromatic_compounds/9508895
<p>The Ag(I)-catalyzed decarboxylative homocoupling from the difluoroacetate has been developed to the synthesis of symmetric CF<sub>2</sub>–CF<sub>2</sub> containing dimers. This radical dimerization overpasses the prefunctionalization of the substrate and provides a direct and efficient method for construction of tetrafluoroethylene bridge-linked homodimers.</p>