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Fate of mercury in a terrestrial biological lab process using Polypogon monspeliensis and Cyperus odoratus

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Version 2 2020-02-19, 07:23
Version 1 2019-06-05, 11:00
journal contribution
posted on 2020-02-19, 07:23 authored by Héctor Daniel García-Mercado, Georgina Fernández-Villagómez, Marco Antonio Garzón-Zúñiga, María del Carmen Durán-Domínguez-de-Bazúa

Mercury has been extracted in Queretaro, Mexico since the 1960s. The mining wastes were open-air disposal and these mercury wastes have polluted the zone. The aim of this research was to evaluate mercury's fate in lab scale terrestrial reactors considering the following mercury species: soluble, interchangeable, strongly bound, organic, and residual ones. Soils were sampled in two former mines of Pinal de Amoles, Queretaro, Mexico (N 20° 58′ to 21° 21′ and West 99° 26′ to 99° 43′) with initial mercury concentrations were 424 ± 29 and 433 ± 12 mg kg−1 for “La Lorena” and “San Jose” former mines, respectively. Two vegetal species Polypogon monspeliensis and Cyperus odoratus were used and 20 reactors were constructed for the lab process. Total mercury was removed to 49–79% from both soils. Mercury elemental, exchangeable, and organic species had the most removal or exchange in the process. Metal uptake, by the plants, was of 5–6% for P. monspeliensis and 5–15% for C. odoratus. Also, mercury fate was estimated to the atmosphere to be 3.3–4.5 mg m−2 h−1 for both soils.

Funding

UNAM DGAPA Programs (in Spanish Programas de Apoyo a Proyectos para la Innovación y Mejoramiento de la Enseñanza, PAPIME, Claves EN103704, PE101709, and PE-100514), and the Programa de Apoyo a la Investigación y el Posgrado de la Facultad de Química de la UNAM, PAIP, Clave 50009067 financially supported the acquisitions of reagents, consumable items, and materials used in this research.

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