Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand

Ritter, Michaela; Molad, Anat; Rawat, Varun; Vigalok, Arkadi; Limberg, Christian

doi:10.6084/m9.figshare.963289.v4

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Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand

Version 4 2014-06-18, 17:42

Version 3 2014-06-18, 17:42

Version 2 2014-06-18, 15:12

Version 1 2014-06-18, 17:42

journal contribution

posted on 2014-06-18, 17:42 authored by Michaela Ritter, Anat Molad, Varun Rawat, Arkadi Vigalok, Christian Limberg

The synthesis and characterisation of an asymmetrically substituted calix-triazole ligand are reported. The ligand reacts with the Fe(II) precursor Fe₂Mes₄ to yield an iron(II) calixarene complex that is oxidised by dioxygen to provide a dinuclear Fe(III) compound featuring an oxido bridge.