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Selective fluorescence sensing and photocatalytic properties of a silver(I)-based metal-organic framework based on 9,10-anthraquinone-1,5-dicarboxylic acid and 4,4'-bipyridine ligands
posted on 2019-10-12, 05:47authored byJun-Jie Wang, Yan Chen, Pan-Pan Si, Rui-Yang Fan, Jie Yang, Ya-Ya Pan, Shan-Shan Zhao, Yun-Feng Shi
Solvothermal reactions of AgNO3 with 9,10-anthraquinone-1,5-dicarboxylic acid (H2L) and 4,4'-bipyridine (bipy) gave rise to a metal-organic framework, namely [Ag(L)(bipy)]n (1), which was structurally characterized by elemental analyses, IR spectra, and X-ray diffraction analysis. Single-crystal X-ray diffraction analyses indicate that 1 exhibits a 2D 44 topology framework assembled by dinuclear [Ag2(COO)2] units, L and bipy ligands. 1 displays highly sensitivity in the detection of nitrobenzene (NB) as a fluorescent sensor. Moreover, 1 exhibits a relatively good photocatalytic activity towards the degradation of rhodamine B (RhB) in aqueous solution under UV irradiation.
Funding
This work was supported the National Natural Science Foundation of China (No. 21403006), the Natural Science Foundation of Henan province (No. 182300410212), the project of Science and Technology Department of Henan Province (No. 182102310636) and the plan of Science and Technology Innovation Team of Henan University (No. 18IRTSTHN006).