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Synthesis and redox properties of sterically crowded triarylphosphine bearing two phenothiazine moieties

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journal contribution
posted on 2019-02-20, 13:13 authored by Shigeru Sasaki, Midori Murakami, Masaaki Yoshifuji

The sterically crowded triarylphosphine bearing two phenothiazine moieties as redox sites was synthesized. The cyclic voltammogram of the phosphine exhibits three-step reversible oxidation, and the comparison with that of the triarylphosphine bearing one phenothiazine moiety suggests delocalization of positive charges during redox process.

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