lsyc_a_888081_sm3275.pdf (2.93 MB)
TBHP-Mediated Oxidative Cross-Coupling of Disulfides with Ethers through a C(sp3)-H Thiolation Process
Version 2 2014-06-09, 18:53
Version 1 2014-06-09, 18:53
journal contribution
posted on 2014-06-09, 18:53 authored by Ya-Ping Hu, Ri-Yuan TangA new tert-butyl hydroperoxide (TBHP)–mediated oxidative cross-coupling of disulfides with ethers is presented for the synthesis of etherified sulfides. This method is achieved by a C(sp3)-H thiolation strategy under metal-free conditions and provides a simple route to constructing the C-S bonds.