data_w276
_audit_creation_date               2019-06-12
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2018/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C20 H22 Cu Dy N5 O15'
_chemical_formula_sum              'C20 H22 Cu Dy N5 O15'
_chemical_formula_weight           798.46
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cu' 'Cu' 0.3201 1.2651 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Dy' 'Dy' -0.1892 4.4098
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             14
_space_group_name_H-M_alt          'P 1 21/c 1'
_space_group_name_Hall             '-P 2ybc'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x, -y-1/2, z-1/2'

_cell_length_a                     12.4772(9)
_cell_length_b                     9.7307(7)
_cell_length_c                     21.9059(17)
_cell_angle_alpha                  90
_cell_angle_beta                   93.201(2)
_cell_angle_gamma                  90
_cell_volume                       2655.5(3)
_cell_formula_units_Z              4
_cell_measurement_reflns_used      9362
_cell_measurement_temperature      273(2)
_cell_measurement_theta_max        27.14
_cell_measurement_theta_min        2.78
_shelx_estimated_absorpt_T_max     ?
_shelx_estimated_absorpt_T_min     ?
_exptl_absorpt_coefficient_mu      3.677
_exptl_absorpt_correction_T_max    ?
_exptl_absorpt_correction_T_min    ?
_exptl_absorpt_correction_type     'none'
_exptl_absorpt_process_details     ?
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              green 
_exptl_crystal_density_diffrn      1.997
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               1568
_exptl_crystal_size_max            0.18
_exptl_crystal_size_mid            0.13
_exptl_crystal_size_min            0.11
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0341
_diffrn_reflns_av_unetI/netI       0.0239
_diffrn_reflns_Laue_measured_fraction_full  0.996
_diffrn_reflns_Laue_measured_fraction_max  0.992
_diffrn_reflns_limit_h_max         16
_diffrn_reflns_limit_h_min         -16
_diffrn_reflns_limit_k_max         12
_diffrn_reflns_limit_k_min         -12
_diffrn_reflns_limit_l_max         28
_diffrn_reflns_limit_l_min         -28
_diffrn_reflns_number              37252
_diffrn_reflns_point_group_measured_fraction_full  0.996
_diffrn_reflns_point_group_measured_fraction_max  0.992
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           27.222
_diffrn_reflns_theta_min           2.656
_diffrn_ambient_temperature        273.15
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.996
_diffrn_measured_fraction_theta_max  0.992
_diffrn_measurement_device_type    'Bruker APEX-II CCD'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     ?
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  5262
_reflns_number_total               5889
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT V8.38A (?, 2016)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT V8.38A (?, 2016)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max           3.266
_refine_diff_density_min           -1.689
_refine_diff_density_rms           0.173
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.178
_refine_ls_hydrogen_treatment      mixed
_refine_ls_matrix_type             full
_refine_ls_number_parameters       386
_refine_ls_number_reflns           5889
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0574
_refine_ls_R_factor_gt             0.0520
_refine_ls_restrained_S_all        1.178
_refine_ls_shift/su_max            0.000
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0186P)²+39.8102P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.1315
_refine_ls_wR_factor_ref           0.1342
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, {H10A,H10B} of C10, {H19A,H19B} of C19, {H11A,H11B} of C11,
   {H7A,H7B} of C7
 At 1.5 times of:
  All C(H,H,H) groups, {H8A,H8B} of C8
2.a Secondary CH2 refined with riding coordinates:
 C19(H19A,H19B), C11(H11A,H11B), C7(H7A,H7B), C10(H10A,H10B)
2.b Aromatic/amide H refined with riding coordinates:
 C9(H9), C5(H5), C18(H18), C12(H12), C3(H3), C4(H4), C16(H16), C17(H17)
2.c Idealised Me refined as rotating group:
 C20(H20A,H20B,H20C)
;
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Dy1 Dy 0.22172(3) 0.29818(4) 0.38625(2) 0.03069(12) Uani 1 1 d . . . A 1
 Cu1 Cu 0.27205(8) 0.39515(10) 0.53560(4) 0.0322(2) Uani 1 1 d . . . . .
 O5 O 0.2203(5) 0.2364(6) 0.4906(2) 0.0339(12) Uani 1 1 d . . . . .
 O6 O 0.1674(5) 0.0561(6) 0.4079(2) 0.0356(12) Uani 1 1 d . . . . .
 O1 O 0.3105(5) 0.4475(6) 0.4548(2) 0.0354(12) Uani 1 1 d . . . . .
 O9 O 0.1399(6) 0.5203(7) 0.3620(3) 0.0504(16) Uani 1 1 d . . . . .
 O2 O 0.3603(5) 0.4480(6) 0.3405(3) 0.0410(14) Uani 1 1 d . . . . .
 O14 O 0.3292(6) 0.1510(6) 0.3209(3) 0.0479(16) Uani 1 1 d . . . . .
 O10 O 0.0410(5) 0.2537(7) 0.3367(3) 0.0454(15) Uani 1 1 d . . . . .
 O7 O 0.0787(5) 0.4220(7) 0.4407(3) 0.0511(16) Uani 1 1 d . . . . .
 O3 O 0.2945(6) 0.6288(8) 0.6247(3) 0.0543(18) Uani 1 1 d . . . . .
 N1 N 0.3153(6) 0.5785(7) 0.5663(3) 0.0366(15) Uani 1 1 d . . . . .
 O11 O 0.1600(5) 0.3085(9) 0.2758(3) 0.0569(18) Uani 1 1 d . . . . .
 O4 O 0.2784(5) 0.3612(7) 0.6690(3) 0.0436(14) Uani 1 1 d . . . . .
 O13 O 0.3965(5) 0.1835(8) 0.4110(3) 0.0507(16) Uani 1 1 d . . . . .
 N2 N 0.2397(6) 0.3066(8) 0.6123(3) 0.0366(15) Uani 1 1 d . . . . .
 N3 N 0.0760(6) 0.5231(8) 0.4050(4) 0.0461(18) Uani 1 1 d . . . . .
 N4 N 0.0622(7) 0.2878(9) 0.2834(3) 0.0487(19) Uani 1 1 d . . . . .
 N5 N 0.4056(7) 0.1358(8) 0.3590(4) 0.0469(18) Uani 1 1 d . . . . .
 O8 O 0.0134(6) 0.6181(8) 0.4098(4) 0.069(2) Uani 1 1 d . . . . .
 C6 C 0.4050(6) 0.5518(8) 0.3774(4) 0.0332(16) Uani 1 1 d . . . . .
 C15 C 0.1555(6) 0.0170(9) 0.4675(4) 0.0343(17) Uani 1 1 d . . . . .
 C1 C 0.3758(6) 0.5491(8) 0.4381(4) 0.0321(16) Uani 1 1 d . . . . .
 C9 C 0.3776(7) 0.6641(9) 0.5396(4) 0.0404(19) Uani 1 1 d . . . . .
 H9 H 0.401755 0.740387 0.561964 0.048 Uiso 1 1 calc R . . . .
 C20 C 0.2252(8) -0.1502(10) 0.3543(5) 0.051(2) Uani 1 1 d . . . . .
 H20A H 0.197439 -0.225187 0.329689 0.077 Uiso 1 1 calc GR . . . .
 H20B H 0.247451 -0.183473 0.394280 0.077 Uiso 1 1 calc GR . . . .
 H20C H 0.285544 -0.110357 0.335515 0.077 Uiso 1 1 calc GR . . . .
 C5 C 0.4732(6) 0.6535(10) 0.3579(4) 0.0406(19) Uani 1 1 d . . . . .
 H5 H 0.493753 0.654203 0.317741 0.049 Uiso 1 1 calc R . . . .
 O15 O 0.4876(7) 0.0756(10) 0.3460(5) 0.084(3) Uani 1 1 d . . . . .
 C18 C 0.1299(7) -0.0389(9) 0.5897(4) 0.0407(19) Uani 1 1 d . . . . .
 H18 H 0.122399 -0.058492 0.630810 0.049 Uiso 1 1 calc R . . . .
 O12 O -0.0054(7) 0.3025(13) 0.2426(4) 0.095(3) Uani 1 1 d . . . . .
 C12 C 0.2015(7) 0.1860(9) 0.6201(4) 0.0375(18) Uani 1 1 d . . . . .
 H12 H 0.192758 0.158501 0.660160 0.045 Uiso 1 1 calc R . . . .
 C13 C 0.1709(6) 0.0897(9) 0.5729(4) 0.0339(17) Uani 1 1 d . . . . .
 C2 C 0.4120(6) 0.6506(9) 0.4785(4) 0.0353(17) Uani 1 1 d . . . . .
 C3 C 0.4809(7) 0.7545(10) 0.4572(4) 0.045(2) Uani 1 1 d . . . . .
 H3 H 0.505836 0.823598 0.483715 0.054 Uiso 1 1 calc R . . . .
 C19 C 0.1393(7) -0.0433(9) 0.3597(4) 0.0384(18) Uani 1 1 d . . . . .
 H19A H 0.128455 0.004698 0.320976 0.046 Uiso 1 1 calc R . . . .
 H19B H 0.072331 -0.088004 0.368330 0.046 Uiso 1 1 calc R . . . .
 C14 C 0.1846(6) 0.1169(8) 0.5109(4) 0.0331(16) Uani 1 1 d . . . . .
 C4 C 0.5105(7) 0.7535(10) 0.3983(4) 0.045(2) Uani 1 1 d . . . . .
 H4 H 0.556503 0.821235 0.385166 0.054 Uiso 1 1 calc R . . . .
 C11 C 0.2072(8) 0.4688(11) 0.6883(4) 0.048(2) Uani 1 1 d . . . . .
 H11A H 0.236128 0.506529 0.726813 0.058 Uiso 1 1 calc R . . . .
 H11B H 0.137855 0.428682 0.695525 0.058 Uiso 1 1 calc R . . . .
 C16 C 0.1132(7) -0.1082(9) 0.4851(4) 0.0418(19) Uani 1 1 d . . . . .
 H16 H 0.093080 -0.173778 0.455753 0.050 Uiso 1 1 calc R . . . .
 C7 C 0.3805(8) 0.4517(11) 0.2754(4) 0.049(2) Uani 1 1 d . . . . .
 H7A H 0.361951 0.363654 0.256905 0.058 Uiso 1 1 calc R . . . .
 H7B H 0.456118 0.468399 0.270400 0.058 Uiso 1 1 calc R . . . .
 C17 C 0.1012(7) -0.1349(10) 0.5467(4) 0.046(2) Uani 1 1 d . . . . .
 H17 H 0.073297 -0.218807 0.558587 0.056 Uiso 1 1 calc R . . . .
 C8 C 0.3121(11) 0.5678(15) 0.2428(6) 0.071(3) Uani 1 1 d . . . . .
 H8A H 0.322(11) 0.581(15) 0.194(7) 0.106 Uiso 1 1 d R . . . .
 H8B H 0.346(12) 0.660(16) 0.264(7) 0.106 Uiso 1 1 d R . . . .
 C10 C 0.1914(8) 0.5843(10) 0.6427(5) 0.048(2) Uani 1 1 d . . . . .
 H10A H 0.148198 0.552770 0.607268 0.057 Uiso 1 1 calc R . . . .
 H10B H 0.154186 0.660157 0.661010 0.057 Uiso 1 1 calc R . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Dy1 O5 2.365(5) . ?
 Dy1 O6 2.504(5) . ?
 Dy1 O1 2.326(5) . ?
 Dy1 O9 2.437(7) . ?
 Dy1 O2 2.513(6) . ?
 Dy1 O14 2.472(7) . ?
 Dy1 O10 2.485(6) . ?
 Dy1 O7 2.509(7) . ?
 Dy1 O11 2.500(7) . ?
 Dy1 O13 2.483(7) . ?
 Dy1 N3 2.889(8) . ?
 Dy1 N5 2.876(8) . ?
 Cu1 O5 1.924(6) . ?
 Cu1 O1 1.927(5) . ?
 Cu1 N1 1.971(7) . ?
 Cu1 N2 1.951(7) . ?
 O5 C14 1.331(9) . ?
 O6 C15 1.376(9) . ?
 O6 C19 1.461(9) . ?
 O1 C1 1.346(9) . ?
 O9 N3 1.268(10) . ?
 O2 C6 1.391(10) . ?
 O2 C7 1.461(10) . ?
 O14 N5 1.240(10) . ?
 O10 N4 1.257(10) . ?
 O7 N3 1.257(10) . ?
 O3 N1 1.407(9) . ?
 O3 C10 1.434(11) . ?
 N1 C9 1.300(10) . ?
 O11 N4 1.257(10) . ?
 O4 N2 1.410(8) . ?
 O4 C11 1.452(11) . ?
 O13 N5 1.243(10) . ?
 N2 C12 1.282(11) . ?
 N3 O8 1.219(10) . ?
 N4 O12 1.202(10) . ?
 N5 O15 1.225(10) . ?
 C6 C1 1.400(11) . ?
 C6 C5 1.388(11) . ?
 C15 C14 1.394(11) . ?
 C15 C16 1.390(12) . ?
 C1 C2 1.384(11) . ?
 C9 C2 1.434(12) . ?
 C20 C19 1.504(12) . ?
 C5 C4 1.379(13) . ?
 C18 C13 1.409(11) . ?
 C18 C17 1.360(13) . ?
 C12 C13 1.431(12) . ?
 C13 C14 1.402(11) . ?
 C2 C3 1.423(11) . ?
 C3 C4 1.363(13) . ?
 C11 C10 1.509(13) . ?
 C16 C17 1.392(13) . ?
 C7 C8 1.564(16) . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 O5 Dy1 O6 63.97(18) . . ?
 O5 Dy1 O9 114.3(2) . . ?
 O5 Dy1 O2 125.15(19) . . ?
 O5 Dy1 O14 116.5(2) . . ?
 O5 Dy1 O10 108.8(2) . . ?
 O5 Dy1 O7 67.6(2) . . ?
 O5 Dy1 O11 158.0(2) . . ?
 O5 Dy1 O13 74.2(2) . . ?
 O5 Dy1 N3 91.0(2) . . ?
 O5 Dy1 N5 96.3(2) . . ?
 O6 Dy1 O2 145.2(2) . . ?
 O6 Dy1 O7 98.9(2) . . ?
 O6 Dy1 N3 120.4(2) . . ?
 O6 Dy1 N5 75.5(2) . . ?
 O1 Dy1 O5 64.09(18) . . ?
 O1 Dy1 O6 126.11(18) . . ?
 O1 Dy1 O9 76.4(2) . . ?
 O1 Dy1 O2 65.31(18) . . ?
 O1 Dy1 O14 118.8(2) . . ?
 O1 Dy1 O10 141.1(2) . . ?
 O1 Dy1 O7 73.6(2) . . ?
 O1 Dy1 O11 135.2(2) . . ?
 O1 Dy1 O13 76.0(2) . . ?
 O1 Dy1 N3 73.5(2) . . ?
 O1 Dy1 N5 96.9(2) . . ?
 O9 Dy1 O6 139.6(2) . . ?
 O9 Dy1 O2 71.8(2) . . ?
 O9 Dy1 O14 128.4(2) . . ?
 O9 Dy1 O10 72.6(2) . . ?
 O9 Dy1 O7 51.5(2) . . ?
 O9 Dy1 O11 69.5(3) . . ?
 O9 Dy1 O13 143.0(2) . . ?
 O9 Dy1 N3 25.8(2) . . ?
 O9 Dy1 N5 140.5(2) . . ?
 O2 Dy1 N3 94.0(2) . . ?
 O2 Dy1 N5 70.2(2) . . ?
 O14 Dy1 O6 74.1(2) . . ?
 O14 Dy1 O2 72.4(2) . . ?
 O14 Dy1 O10 98.9(2) . . ?
 O14 Dy1 O7 167.5(2) . . ?
 O14 Dy1 O11 67.1(2) . . ?
 O14 Dy1 O13 50.8(2) . . ?
 O14 Dy1 N3 152.5(2) . . ?
 O14 Dy1 N5 25.4(2) . . ?
 O10 Dy1 O6 70.8(2) . . ?
 O10 Dy1 O2 123.7(2) . . ?
 O10 Dy1 O7 68.9(2) . . ?
 O10 Dy1 O11 50.3(2) . . ?
 O10 Dy1 N3 68.3(2) . . ?
 O10 Dy1 N5 121.9(2) . . ?
 O7 Dy1 O2 115.8(2) . . ?
 O7 Dy1 N3 25.7(2) . . ?
 O7 Dy1 N5 163.6(2) . . ?
 O11 Dy1 O6 98.6(2) . . ?
 O11 Dy1 O2 76.8(2) . . ?
 O11 Dy1 O7 104.6(2) . . ?
 O11 Dy1 N3 86.8(2) . . ?
 O11 Dy1 N5 91.5(2) . . ?
 O13 Dy1 O6 77.3(2) . . ?
 O13 Dy1 O2 74.5(2) . . ?
 O13 Dy1 O10 141.4(2) . . ?
 O13 Dy1 O7 138.7(2) . . ?
 O13 Dy1 O11 116.7(2) . . ?
 O13 Dy1 N3 149.5(2) . . ?
 O13 Dy1 N5 25.5(2) . . ?
 N5 Dy1 N3 164.0(2) . . ?
 O5 Cu1 Dy1 41.61(16) . . ?
 O5 Cu1 O1 80.5(2) . . ?
 O5 Cu1 N1 168.2(3) . . ?
 O5 Cu1 N2 90.4(3) . . ?
 O1 Cu1 Dy1 40.40(16) . . ?
 O1 Cu1 N1 89.8(3) . . ?
 O1 Cu1 N2 169.0(3) . . ?
 N1 Cu1 Dy1 127.3(2) . . ?
 N2 Cu1 Dy1 131.7(2) . . ?
 N2 Cu1 N1 99.9(3) . . ?
 Cu1 O5 Dy1 105.7(2) . . ?
 C14 O5 Dy1 124.5(5) . . ?
 C14 O5 Cu1 129.7(5) . . ?
 C15 O6 Dy1 119.0(5) . . ?
 C15 O6 C19 118.0(6) . . ?
 C19 O6 Dy1 122.8(5) . . ?
 Cu1 O1 Dy1 107.1(2) . . ?
 C1 O1 Dy1 123.9(5) . . ?
 C1 O1 Cu1 129.0(5) . . ?
 N3 O9 Dy1 97.5(5) . . ?
 C6 O2 Dy1 116.8(4) . . ?
 C6 O2 C7 117.6(7) . . ?
 C7 O2 Dy1 124.3(5) . . ?
 N5 O14 Dy1 95.8(5) . . ?
 N4 O10 Dy1 97.3(5) . . ?
 N3 O7 Dy1 94.3(5) . . ?
 N1 O3 C10 111.1(7) . . ?
 O3 N1 Cu1 124.3(5) . . ?
 C9 N1 Cu1 125.9(6) . . ?
 C9 N1 O3 109.3(7) . . ?
 N4 O11 Dy1 96.6(5) . . ?
 N2 O4 C11 110.1(6) . . ?
 N5 O13 Dy1 95.2(5) . . ?
 O4 N2 Cu1 121.0(6) . . ?
 C12 N2 Cu1 128.0(6) . . ?
 C12 N2 O4 109.8(7) . . ?
 O9 N3 Dy1 56.7(4) . . ?
 O7 N3 Dy1 60.0(4) . . ?
 O7 N3 O9 116.7(8) . . ?
 O8 N3 Dy1 176.9(7) . . ?
 O8 N3 O9 121.0(9) . . ?
 O8 N3 O7 122.3(9) . . ?
 O10 N4 Dy1 57.5(4) . . ?
 O10 N4 O11 114.9(7) . . ?
 O11 N4 Dy1 58.1(4) . . ?
 O12 N4 Dy1 171.0(9) . . ?
 O12 N4 O10 123.1(9) . . ?
 O12 N4 O11 121.9(9) . . ?
 O14 N5 Dy1 58.8(4) . . ?
 O14 N5 O13 117.8(8) . . ?
 O13 N5 Dy1 59.3(4) . . ?
 O15 N5 Dy1 175.1(7) . . ?
 O15 N5 O14 121.5(9) . . ?
 O15 N5 O13 120.8(9) . . ?
 O2 C6 C1 115.0(7) . . ?
 C5 C6 O2 124.9(8) . . ?
 C5 C6 C1 120.1(8) . . ?
 O6 C15 C14 114.6(7) . . ?
 O6 C15 C16 124.6(8) . . ?
 C16 C15 C14 120.7(8) . . ?
 O1 C1 C6 117.8(7) . . ?
 O1 C1 C2 122.1(7) . . ?
 C2 C1 C6 120.1(7) . . ?
 N1 C9 C2 125.3(8) . . ?
 C4 C5 C6 119.8(8) . . ?
 C17 C18 C13 121.0(8) . . ?
 N2 C12 C13 126.1(7) . . ?
 C18 C13 C12 118.6(7) . . ?
 C14 C13 C18 119.1(8) . . ?
 C14 C13 C12 122.2(7) . . ?
 C1 C2 C9 123.9(7) . . ?
 C1 C2 C3 118.6(8) . . ?
 C3 C2 C9 117.3(8) . . ?
 C4 C3 C2 120.4(9) . . ?
 O6 C19 C20 111.8(7) . . ?
 O5 C14 C15 117.5(7) . . ?
 O5 C14 C13 123.3(7) . . ?
 C15 C14 C13 119.1(7) . . ?
 C3 C4 C5 120.9(8) . . ?
 O4 C11 C10 113.8(7) . . ?
 C15 C16 C17 119.7(8) . . ?
 O2 C7 C8 110.1(8) . . ?
 C18 C17 C16 120.3(8) . . ?
 O3 C10 C11 108.8(8) . . ?

_olex2_submission_special_instructions  'No special instructions were received'
