gpss_a_1759062_sm9840.docx (22.83 MB)
Interaction of 1-acylamino-2,2-dichloroethenyl(triphenyl)phosphonium chlorides with alkanolamines
journal contribution
posted on 2020-05-12, 09:19 authored by O. V. Golovchenko, E. R. Abdurakhmanova, S. O. Vladimirov, M. Y. Brusnakov, T. O. Krupoder, V. V. Sukhoveev, E. B. Rusanov, R. N. Vydzhak, V. S. BrovaretsIt is shown that the interaction of 1-acylamino-2,2-dichloroethenyl(triphenyl)-phosphonium chlorides with alkanolamines having a primary amino group results in the formation of 4-oxazolylphosphonium salts containing hydroxyalkylamine substituents at position 5 of the oxazole cycle. Under similar conditions the reaction of N-substituted alkanolamines with 1-acylamino-2,2-dichloroethenyl-(triphenyl)phosphonium chlorides leads to the formation of 1,3-oxazolidin-2-ylidene derivatives, in which the triphenylphosphonium group is located in the side chain. The structure of the new synthesized compounds has been reliably proven by elemental analysis, IR, 1Н, 13С, 31Р NMR spectroscopy, mass spectrometry and single crystal X-ray diffraction.