lsyc_a_1651865_sm7182.docx (4.84 MB)
Silver-catalyzed decarboxylative homocoupling reaction for the construction of tetrafluoroethylene-bridging aromatic compounds
journal contribution
posted on 2019-08-12, 07:39 authored by Yong Wang, Huaxin Zhao, Xiaojuan Xie, Haizhen Jiang, Hongmei Deng, Jian Hao, Wen WanThe Ag(I)-catalyzed decarboxylative homocoupling from the difluoroacetate has been developed to the synthesis of symmetric CF2–CF2 containing dimers. This radical dimerization overpasses the prefunctionalization of the substrate and provides a direct and efficient method for construction of tetrafluoroethylene bridge-linked homodimers.